SYNTHESIS AND CHARACTERIZATION OF Co(Ⅱ) COMPLEX OF 14-MEMBERED HEXAAZA MACROCYCLIC LIGAND WITH AXIALLY COORDINATED BROMIDES

The macrocyclic ligand complex, [Co(C_(18)H_(18)N_6) Br_2]·1/2H_2O, has been synthesized by the template condensation of 2, 6-diacetylpyridine with hydrazine in the presence of cobalt (Ⅱ) dibromide and characterized by IR, ESR, electronic spectra and magnetic properties. Based on these data, the complex is proposed to be an approximate elongated octahedron with low spin state. The absorption bands of d-d transition are assigned, and the values of various ligand field parameters have been evaluated and are discussed in terms of their chemical utilities. ESR study on the complex has been carried out. The values of g(?)and g(?) have been determined. From ligand field parameter values and gvalues, μ_(eff)=2.06 BM has been obtained, which is consistent with the experimental value(2.04BM).     

Ni-Mg,Mg-Mn和Ni-Zn三种铁氧体在3厘米波段的法拉第旋转及衰耗

Faraday rotation and loss characteristics at 9200 me and at room temperature of Ni-Mg, Mg-Mn and Ni-Zn ferrite rods and disks placed in a circular waveguide are measured as a function of applied longitudinal DC magnetic field.Of particular interest are the results obtained with a new type of Ni-Mg ferrites, since very little data on Ni-Mg ferrites have been published in the literature. In this paper sufficient data are given on Faraday rotation and loss characteristics of a complete range of nickel-magnesium ferrites with composition varying from pure nickel to pure magnesium. Experimental results at 9200 me indicate that for the sintering temperature of 1300℃, the best composition range for nickel-magnesium ferrites would be Ni_0.7Mg_0.3Fe₂O₄-Ni_0.8Mg_0.2Fe₂O₄. In future, nickel-magnesium ferrites, due to their very low loss, may find practical applications in the microwave field.Comparison information as to the relative merits of these three useful microwave ferrites are given in the form of curves and tables, and their results are discussed in some detail.This paper also gives a summary of the linear theory on Faraday rotation of a linearly polarized wave propagating in ferrite-loaded waveguide which is longitudinally magnetized.     

OTR时间分辨测量系统的嵌入式远程控制方法

 基于光学渡越辐射原理的高能强流电子束束流参数在线测量及诊断系统，具有时间响应快、分辨率高的特点，可以测量电子束的束剖面、发射角、能量等参数。利用嵌入式方法，通过计算机控制系统对时间分辨测量系统实现实时的远程控制，实现了直线感应加速器中时间分辨测量。计算机控制系统接收光电视频信号，进行实时图像传输，得到动态图像，有效解决了在直线感应加速器中强流干扰的光学渡越辐射测量的困难。并给出了嵌入式远程控制的方法。     

金属铝在半导体表面的吸附

本文采用集团模型,用自洽的EHT方法计算金属Al在Si(111)和GaAs(110)面上吸附的稳定的几何构型和电子态,结果表明,Al在Si(111)面的三度开位上的离子吸附比顶位的共价吸附更稳定,态密度与实验符合也更好,Al吸附在GaAs(110)面上,将取代表面Ga原子,形成AlAs,此时GaAs(110)面将恢复到不弛豫的理想位置。 关键词：     

轻微形变晶体X射线衍射动力学方程的微扰解

用微扰方法讨论了高木(S.Takagi)方程,得到了球面入射波情况下轻微形变晶体衍射振幅的微扰解。 关键词：     

化学淀积银膜上的吡啶表面增强喇曼散射效应——银膜结构的影响

本文考察了由化学淀积法制得的不同厚度银膜上吸附的吡啶产生的SERS效应。结果表明金属银膜层的几何结构对增强效应产生极大影响,且增强效应不仅取决于银颗粒的大小,而且还与它们的间隔有关。我们借用了Wirgin提出的波导共振理论对实验现象作了定性解释,计算结果与实验结果基本相符。     

含时阻尼线性谐振子的量子不变量处理

在适当的正则化变换下,采用Lewis-Riesenfeld量子不变量理论,得到了含时阻尼线性谐振子的精确波函数,波函数的正确性和普遍性同样得到讨论.     

高介电常数复合介质固态Blumlein线

 以陶瓷聚合物复合介质作为储能介质，砷化镓光导半导体开关作为开关，设计了带状Blumlein线并对其进行了实验研究。实验结果表明，复合介质Blumlein介电常数高达80～250，在21 Ω的匹配负载上获得电压幅值为2 kV，前沿小于5 ns，半高宽约34 ns，波动约±1%的平顶宽为22 ns的电压脉冲，能满足脉冲功率系统小型化的应用要求。     

固定设计函数型非参数回归模型的估计

本文研究一类固定设计函数型非参数回归模型回归算予的估计问题,其中,解释变量X是取值于某函数空间的函数型变量,响应变量y为实值随机变量,在误差是一弱平稳线性过程及适当的条件下,获得未知回归函数算子估计量的相合性及其收敛速度和渐近正态性,推广了现有文献中的相关结果.     

锂硫电池中的催化作用:材料与表征

锂硫电池是高能量密度储能体系的重要发展方向, 但其本征的“固-液-固”转化过程缓慢, 穿梭效应的存在使其循环寿命和能量密度远低于理论值. 如何加速硫的可逆反应成为实现锂硫电池变革性突破的关键. 近年来, 催化过程在锂硫电池研究中崭露头角, 高效催化剂的引入能够降低硫转化的势垒, 加速“固-液-固”转化进程, 提高硫的利用率, 从“准源头”上降低穿梭效应发生的概率, 减少电解液需求量, 提升锂硫电池整体性能. 本文综合评述了锂硫电池中高效催化材料的研究进展, 提出原位表征技术对催化机理研究的重要性和紧迫性, 并对锂硫电池未来的技术发展趋势进行了展望.